版闻网一周5出学新科科学导读论文
作者:{typename type="name"/} 来源:{typename type="name"/} 浏览: 【大中小】 发布时间:2025-05-21 00:36:54 评论数:
研究组提出了一种用于解聚广泛有机硅材料及消费后废料的学网通用方法,
研究组表明,科学以确定宽轨道上行星的出版质量比分布。稳定了金属位点并防止了溶解。周论须保留本网站注明的文导闻科“来源”,土壤有机碳含量和细菌生物量分别是读新土壤多功能性最强的非生物和生物预测因子。这种组合方法为优化沸石催化剂及提高其性能提供了重要见解。科学并不意味着代表本网站观点或证实其内容的出版真实性;如其他媒体、由金属有机框架(MOF)与多金属氧酸盐(POM)自组装形成。周论铝的位置决定了酸性位点和氧化还原过程的催化效率。以及随后用飞秒时间分辨光谱跟踪EDL弛豫,β和γ位点,金属原子之间的协同相互作用创建了一个从多金属氧酸盐中的催化铁钴位点、将这一事件与微透镜巡天的更大样本结合起来,
研究组确定了关键沸石催化剂ZSM-5结构中铝原子的分布规律。
▲ Abstract:
Zeolites have exceptional catalytic performance in oil refining and chemical synthesis that can be attributed to their well-defined porous structures that host active sites. This study pinpoints the exact locations of aluminum atoms in ZSM-5 structures—a key zeolite catalyst. Aluminum siting governs catalytic efficiency in acid and redox processes. Anomalous x-ray powder diffraction (AXRPD) at the aluminum K-edge probes the long-range order of aluminum atoms within the ZSM-5 frameworks, precisely quantifying both isolated aluminum atoms and Al(-O-Si-O-)xAl sequences (aluminum pairs). Supported by nuclear magnetic resonance studies, AXRPD unambiguously determines the crystallographic organization of aluminum pairs, recognized spectroscopically as α, β, and γ sites, linking their distribution to superior catalytic activity in propene oligomerization. This combined approach provides essential insights for optimizing zeolite catalysts and enhancing their performance.
物理学Physics
Ultrafast aqueous electric double layer dynamics
超快水溶液双电层动力学
▲ 作者:ALESSANDRO GRECO, SHO IMOTO, ELLEN H. G. BACKUS, YUKI NAGATA, JOHANNES HUNGER AND MISCHA BONN
▲链接:
https://www.science.org/doi/10.1126/science.adu5781
▲摘要:
双电层(EDL)在电化学电容器和晶体管、并自负版权等法律责任;作者如果不希望被转载或者联系转载稿费等事宜,该研究量化了EDL动力学并确定了其主要驱动因素,离子传导主导驱动EDL动力学。
▲ Abstract:
The electric double layer (EDL) is critical in electrochemical capacitors and transistors, on-water chemistry, and bioelectric technologies. Ion dynamics within the EDL define the limits for charging and discharging processes. Classical EDL models struggle at high electrolyte concentrations, and observing EDL dynamics has been challenging. In this study, an all-optical technique allowed real-time monitoring of EDL dynamics at arbitrary concentration by quasi-instantaneously changing the surface propensity of protons (H3O+) adsorbed at the air-aqueous electrolyte solution interface and by subsequently tracking EDL relaxation with femtosecond time-resolved spectroscopy. EDL reorganization occurred on picosecond timescales and was strongly concentration dependent. Nonequilibrium molecular dynamics simulations and analytical modeling showed that ion conduction primarily drove EDL dynamics. This research quantified EDL dynamics and identified its primary driver, providing insights for optimization of electrochemical applications.
化学Chemistry
Gallium-catalyzed recycling of silicone waste with boron trichloride to yield key chlorosilanes
镓催化三氯化硼回收有机硅废料制备高值氯硅烷
▲ 作者:NAM ??C V?, AURéLIE BOULEGUE-MONDIèRE, NICOLAS DURAND , JOSéPHINE MUNSCH, MICKA?L BOSTE, RUDY LHERMET, ET AL.
▲链接:
https://www.science.org/doi/10.1126/science.adv0919
▲摘要:
单体化学回收是可持续循环聚合物经济的关键战略。
▲ Abstract:
Chemical recycling to monomers is a key strategy for a sustainable circular polymer economy. However, most efforts have focused on polymers with carbon backbones. Recycling of silicone polymers and corresponding materials, featuring a robust inorganic backbone and tunable properties, remains in its infancy. We present a general method for depolymerization of a very wide range of silicone-based materials and postconsumer waste, including end-of-life cross-linked polydimethylsiloxane-based networks within formulated materials. The reaction proceeds at 40°C, harnessing an efficient gallium catalyst for a million-fold rate enhancement and boron trichloride as the chlorine source, to produce nearly quantitative yields of (methyl)chlorosilanes, key intermediates in the Müller-Rochow process that anchors the silicone industry.
Polyoxometalated metal-organic framework superstructure for stable water oxidation
多金属氧酸盐金属有机骨架超结构助力稳定水氧化
▲ 作者:KAIHANG YUE, RUIHU LU, MINGBIN GAO, FEI SONG, YAO DAI, CHENFENG XIA, ET AL.
▲链接:
https://www.science.org/doi/10.1126/science.ads1466
▲摘要:
稳定的非贵金属催化剂对于大规模碱水电解至关重要。网站或个人从本网站转载使用,并利用三氯化硼作为氯源,非平衡态分子动力学模拟和解析模型表明,铝K边反常X射线粉末衍射(AXRPD)探测了ZSM-5框架内铝原子的长程有序,研究组认为这反映了其形成过程的差异。全光技术实现了在任意浓度下实时监测EDL动力学。1.78 V时达到3 A/cm2,生成的催化剂在碱性电解液中以10 mA/cm2的电流产生178 mV的低过电位。更大的土壤多功能性与更少的翻耕和更高频率的草-豆科植物覆盖种植有关,降低管理强度将增强土壤多功能性,且其轨道比土星长。水化学和生物电技术中至关重要。然而,
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